Comparison of Calibration Curve Method and Partial Least Square Method in the Laser Induced Breakdown Spectroscopy Quantitative Analysis

Comparison of Calibration Curve Method and Partial Least Square Method in the Laser Induced Breakdown Spectroscopy Quantitative Analysis

The Laser Induced Breakdown Spectroscopy (LIBS) is a fast, non-contact, no sample preparation analytic technology; it is very suitable for on-line analysis of alloy composition. In the copper smelting industry, analysis and control of the copper alloy concentration affect the quality of the products greatly, so LIBS is an efficient quantitative analysis technology in the copper smelting industr...

Quantitative elemental analysis by laser-induced breakdown spectroscopy

Laser-induced breakdown spectroscopy (LIBS) has been popular in elemental analysis for various kinds of samples due to its rapid and in-situ measurement using simple equipment. However, quantitative analysis by LIBS is still inferior to conventional element analysis methods in sensitivity and accuracy. In this paper improvement in LIBS is attempted applying computational processing to low-resol...

Calibration-Free Laser-Induced Breakdown Spectroscopy: State of the art

Calibration free laser-induced breakdown spectroscopy of oxide materials

a r t i c l e i n f o Keywords: Calibration free laser-induced breakdown spectroscopy (CF-LIBS) Multi-element analysis Oxides The quantitative determination of oxide concentration by laser-induced breakdown spectroscopy is relevant in various fields of applications (e.g.: analysis of ores, concrete, slag). Calibration free laser-induced breakdown spectroscopy and the multivariate calibration ar...

Simultaneous Spectrophotometric Determination of Iron, Cobalt and Copper by Partial Least-Squares Calibration Method in Micellar Medium

Iron, cobalt and copper are metals, which appear together in many real samples, both natural and artificial. Recently a classical univariate micellar colorimetric method has been developed for determination of these metal ions. The organized molecular assemblies such as micelles are used in spectroscopic measurements due to their possible effects on the systems of interest. The ability of mi...